Asymmetric Alkoxy and Alkyl Substitution on Nonfullerene Acceptors Enabling High‐Performance Organic Solar Cells. Issue 3 (30th November 2020)

• Record Type: Journal Article
• Authors: Chen, Yuzhong; Bai, Fujin; Peng, Zhengxing; Zhu, Lei; Zhang, Jianquan; Zou, Xinhui; Qin, Yunpeng; Kim, Ha Kyung; Yuan, Jun; Ma, Lik‐Kuen; Zhang, Jie; Yu, Han; Chow, Philip C. Y.; Huang, Fei; Zou, Yingping; Ade, Harald; Liu, Feng; Yan, He
• Is Part Of: Advanced energy materials. Volume 11:Issue 3(2021)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2020-11-30
• Subjects: asymmetric alkoxy substitution -- morphology -- organic solar cells -- solubility -- Y‐series acceptors; Energy harvesting -- Materials -- Periodicals; Energy conversion -- Materials -- Periodicals; Energy storage -- Materials -- Periodicals; Photovoltaics -- Periodicals; Fuel cells -- Periodicals; Thermoelectric materials -- Periodicals; 621.31
• DOI: 10.1002/aenm.202003141
• Languages: English
• ISSNs: 1614-6832

Abstract

Abstract: In this paper, a strategy of asymmetric alkyl and alkoxy substitution is applied to state‐of‐the‐art Y‐series nonfullerene acceptors (NFAs), and it achieves great performance in organic solar cell (OSC) devices. Since alkoxy groups can have a significant influence on the material properties of NFAs, alkoxy substitution is applied to the Y6 molecule in a symmetric manner. The resulting molecule (named Y6‐2O), despite showing improved open‐circuit voltage ( V oc ), yields extremely poor performance due to low solubility and excessive aggregation properties, a change that is due to the conformational locking effect of alkoxy groups. In contrast, asymmetric alkyl and alkoxy substitution on Y6, yields a molecule named Y6‐1O that can maintain the positive effect of V oc improvement and obtain reasonably good solubility. The resulting molecule Y6‐1O enables highly efficient nonfullerene OSCs with 17.6% efficiency and the asymmetric side‐chain strategy has the potential to be applied to other NFA‐material systems to further improve their performance. Abstract : Novel asymmetric alkoxy and alkyl substitutions on the well‐known nonfullerene acceptor Y6 yield a molecule named Y6‐1O, and its photoelectric properties and photovoltaic performance are systematically compared with the two related symmetric molecules (Y6 and Y6‐2O), which suggests that this design strategy is promising and effective.