A host–guest interaction activated Bobbitt oxidant for highly efficient oxidation of alcohols. Issue 92 (1st November 2022)

• Record Type: Journal Article
• Authors: Wu, Jinyang; Luo, Youran; Chen, Lingxuan; Sun, Xuan; Chen, Xinnan; Qin, Song; Feng, Wen; Li, Xiaowei; Yuan, Lihua
• Is Part Of: Chemical communications. Volume 58:Issue 92(2022)
• Page Start: 12867
• Page End: 12870
• Publication Date: 2022-11-01
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/d2cc05027g
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : Host–guest complexation using hydrogen-bonded macrocycles was found to enable activation of the Bobbitt oxidant reagent, which greatly facilitates the highly efficient oxidation of unactivated primary alcohols. Abstract : Host–guest complexation using hydrogen-bonded macrocycles was found to enable activation of the Bobbitt oxidant reagent, which greatly facilitates the highly efficient oxidation of unactivated primary alcohols. This work provides a complementary approach to the activation of Bobbitt's salt with shape-persistent macrocycles in supramolecular catalysis.