A novel core/shell cuprous oxide-based structure with improved microwave absorbing and antibacterial performance. (10th December 2022)

• Record Type: Journal Article
• Authors: Ma, Chengcheng; Wang, Wei; Kong, Debao; Wei, Shuang; Li, Wen; Chen, Shougang
• Is Part Of: Journal of cleaner production. Volume 378(2022)
• Publication Date: 2022-12-10
• Subjects: Cu2O@NiCo2O4/RGO -- Microwave absorption -- Visible light photocatalyst -- Long-term antibacterial activity; Factory and trade waste -- Management -- Periodicals; Manufactures -- Environmental aspects -- Periodicals; Déchets industriels -- Gestion -- Périodiques; Usines -- Aspect de l'environnement -- Périodiques; 628.5
• DOI: 10.1016/j.jclepro.2022.134419
• Languages: English
• ISSNs: 0959-6526

Abstract

Abstract: The cuprous oxide-based (Cu2 O@NiCo2 O4 /RGO) composites were fabricated using a simple approach to achieve superior microwave absorbing (MA) performance and long-term antibacterial activity. The minimum reflection loss (RL) value reached −51.56 dB with an efficient absorption bandwidth (EAB ) of 6.64 GHz. The enhanced MA performance was mainly due to increased interfacial polarization, efficient multiple reflection and scattering, and dipole polarization. Finite element method simulations were adopted to validate the improved MA performance of NiCo2 O4 achieved with Cu2 O and RGO. Its outstanding long-term antibacterial activity against S. aureus and P. aeruginosa is based on the synergistic effect between the continuous release of copper ions and ROS generated by photocatalysis. Density functional theory simulations were used to analyze the regulation of the work function of Cu2 O@NiCo2 O4 /RGO, demonstrating the putative mechanism of ROS production. The Cu2 O@NiCo2 O4 /RGO material is a promising MA antifouling agent for marine. Graphical abstract: Image 1 Highlights: Hybrid composites were synthesized with Cu2 O core and NiCo2 O4 /RGO shell by a two-step method. Superior MA performances with RLmin of −51.56 dB and EAB of 6.64 GHz. Its outstanding long-term antibacterial activity against S. aureus and P. aeruginosa. Improved long-term antibacterial ability due to the photocatalysis, persistent release of Cu 2+ and ROS action.