The Redox Journey of Iconic Ferrocene: Ferrocenium Dications and Ferrocenate Anions. Issue 23 (29th April 2021)

• Record Type: Journal Article
• Authors: Walawalkar, Mrinalini G.; Pandey, Priya; Murugavel, Ramaswamy
• Is Part Of: Angewandte Chemie international edition. Volume 60:Issue 23(2021)
• Page Start: 12632
• Page End: 12635
• Publication Date: 2021-04-29
• Subjects: electrochemistry -- ferrocenate -- ferrocene -- organometallic chemistry -- redox chemistry; Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.202101770
• Languages: English
• ISSNs: 1433-7851

Abstract

Abstract : The recent discoveries of both dicationic and monoanionic ferrocene derivatives throw light on the effect of the substituents on the C5 ring as well as the choice of redox agents and solvent system in the preparation of previously believed to be difficult synthetic targets. These oxidized and reduced forms of ferrocene are of interest to spectroscopists, magnetochemists, and theoreticians.