Lattice Distortion Engineering over Ultrathin Monoclinic BiVO4 Nanoflakes Triggering AQE up to 69.4% in Visible‐Light‐Driven Water Oxidation. (31st August 2022)

• Record Type: Journal Article
• Authors: Philo, Davin; Luo, Shunqin; He, Can; Wang, Qi; Ichihara, Fumihiko; Jia, Lulu; Oshikiri, Mitsutake; Pang, Hong; Wang, Yan; Li, Sijie; Yang, Gaoliang; Ren, Xiaohui; Lin, Huiwen; Ye, Jinhua
• Is Part Of: Advanced functional materials. Volume 32:Number 45(2022)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2022-08-31
• Subjects: lattice distortion -- monoclinic BiVO 4 -- Na + additive -- photocatalytic water oxidation -- ultrathin 2D structures; Materials -- Periodicals; Chemical vapor deposition -- Periodicals; 620.11
• DOI: 10.1002/adfm.202206811
• Languages: English
• ISSNs: 1616-301X

Abstract

Abstract: An efficient water oxidation photocatalyst is imperative for the realization of artificial photosynthesis. Herein, a cooperative strategy is represented that enables 2D structure tailoring and lattice distortion engineering simultaneously over a BiVO4 photocatalyst for efficient visible‐light‐driven oxygen evolution reaction (OER). Specifically, the lattice distortion engineering is achieved through the introduction of a sodium (Na + ) additive during the ion exchange process. Structural characterizations suggest the formation of ultrathin 2D monoclinic BiVO4 nanoflakes with shrank VO and elongated BiO bonds. Mechanistic investigations reveal the advantages of ultrathin 2D features for exposing more (010) active facets and shortening the required migration distance for charge carriers to reach the catalytic surface. More importantly, the lattice distortion effect is found to crucially govern the charge carrier dynamics and catalytic surface behavior of BiVO4 photocatalyst, endowing the optimized sample with an outstanding photocatalytic OER performance triggering up to 69.4% apparent quantum efficiency over Fe 3+ sacrificial solution. These findings highlight the functional application of morphology and dimensional modification, as well as lattice distortion engineering in synthesizing superior monoclinic BiVO4 photocatalyst for efficient visible‐light‐driven water oxidation. Abstract : A cooperative strategy of 2D structure tailoring (by a template‐directed method) and lattice distortion engineering (through the simple introduction of Na + additive) is effectively applied over a monoclinic BiVO4 photocatalyst. The interplay between ultrathin 2D features and lattice distortion effect significantly modulates the charge carrier dynamics and surface catalytic behavior, thus endowing an exceptional enhancement of photocatalytic oxygen evolution performance.