High‐Entropy and Superstructure‐Stabilized Layered Oxide Cathodes for Sodium‐Ion Batteries. Issue 41 (8th September 2022)

• Record Type: Journal Article
• Authors: Yao, Libing; Zou, Peichao; Wang, Chunyang; Jiang, Jiahao; Ma, Lu; Tan, Sha; Beyer, Kevin A.; Xu, Feng; Hu, Enyuan; Xin, Huolin L.
• Is Part Of: Advanced energy materials. Volume 12:Issue 41(2022)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2022-09-08
• Subjects: high‐entropy oxides -- layered materials -- sodium‐ion cathodes -- superlattice; Energy harvesting -- Materials -- Periodicals; Energy conversion -- Materials -- Periodicals; Energy storage -- Materials -- Periodicals; Photovoltaics -- Periodicals; Fuel cells -- Periodicals; Thermoelectric materials -- Periodicals; 621.31
• DOI: 10.1002/aenm.202201989
• Languages: English
• ISSNs: 1614-6832

Abstract

Abstract: Layered transition metal oxides are appealing cathodes for sodium‐ion batteries due to their overall advantages in energy density and cost. But their stabilities are usually compromised by the complicated phase transition and the oxygen redox, particularly when operating at high voltages, leading to poor structural stability and substantial capacity loss. Here an integrated strategy combing the high‐entropy design with the superlattice‐stabilization to extend the cycle life and enhance the rate capability of layered cathodes is reported. It is shown that the as‐prepared high‐entropy Na2/3 Li1/6 Fe1/6 Co1/6 Ni1/6 Mn1/3 O2 cathode enables a superlattice structure with Li/transition metal ordering and delivers excellent electrochemical performance that is not affected by the presence of phase transition and oxygen redox. It achieves a high reversible capacity (171.2 mAh g −1 at 0.1 C), a high energy density (531 Wh kg −1 ), extended cycling stability (89.3% capacity retention at 1 C for 90 cycles and 63.7% capacity retention at 5 C after 300 cycles), and excellent fast‐charging capability (78 mAh g −1 at 10 C). This strategy would inspire more rational designs that can be leveraged to improve the reliability of layered cathodes for secondary‐ion batteries. Abstract : An integrated strategy combing the high‐entropy design with the superlattice‐stabilization is reported to extend the cycle life and enhance the rate capability of layered cathodes. Interestingly, the proposed cathode realized a fast and reversible O3–P3 phase transition at low voltage regions but suppressed phase transition and reversible oxygen redox at high voltage regions.