A silver(I) coordination polymer with bridging bis(thiosemicarbazone) ligands and unsupported argentophilic interactions. Issue 11 (28th October 2022)

• Record Type: Journal Article
• Authors: Crouch, Sophie A.; Davey, Patrick R.W.J.; Forsyth, Craig M.; Batten, Stuart R.; Paterson, Brett M.
• Is Part Of: Journal of coordination chemistry. Volume 75:Issue 11/14(2022)
• Page Start: 1691
• Page End: 1701
• Publication Date: 2022-10-28
• Subjects: Silver -- bis(thiosemicarbazone) -- coordination polymer -- argentophilic -- 3-D network; Coordination compounds -- Periodicals; 541.2242
• DOI: 10.1080/00958972.2022.2092845
• Languages: English
• ISSNs: 0095-8972

Abstract

Abstract: The synthesis and structural characterization of a silver(I) coordination polymer is reported. The structure contains a silver(I) ion coordinated by three sulfur donor atoms from three bridging bis(thiosemicarbazone) ligands in a trigonal planar coordination environment, generating a 2-D coordination polymer. The structure involves hydrogen bonds between the tetrafluoroborate counterion and the ligands and close Ag⋅⋅⋅Ag contacts to create an overall 3-D network. Graphical Abstract: UF0001