A high-TC heavy rare earth monoxide semiconductor TbO with a more than half-filled 4f orbital. Issue 43 (24th October 2022)

• Record Type: Journal Article
• Authors: Sasaki, Satoshi; Oka, Daichi; Kaminaga, Kenichi; Saito, Daichi; Yamamoto, Taku; Abe, Nobuto; Shimizu, Hirokazu; Fukumura, Tomoteru
• Is Part Of: Dalton transactions. Volume 51:Issue 43(2022)
• Page Start: 16648
• Page End: 16652
• Publication Date: 2022-10-24
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/d2dt02710k
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : A rock-salt structured terbium monoxide, TbO, was synthesized for the first time in the solid phase. This TbO is a high T C (231 K) ferromagnetic semiconductor, probably forming 4f and 5f magnetic sublattices at a single magnetic Tb 2+ site. Abstract : Terbium monoxide, TbO, with an unusual valence state of Tb 2+ ([Xe]4f 8 5d 1 ) has been known to exist as a gas phase. In this study, we report a solid phase rock-salt structured TbO in the form of an epitaxial thin film. This TbO is a narrow gap ferromagnetic semiconductor with a bandgap of ∼0.1 eV and high Curie temperature of 231 K, and exhibited negative magnetoresistance of −14% at 9 T and 2 K. Its magnetization steeply increased with the appearance of a wasp-waisted hysteresis curve significantly below the Curie temperature at about 20 K. These results suggested that both 4f and 5d magnetic sublattices were formed at a single magnetic Tb 2+ site in TbO.