A diamantane-4, 9-dicarboxylate based UiO-66 analogue: challenging larger hydrocarbon cage platforms. Issue 43 (12th October 2022)

• Record Type: Journal Article
• Authors: Gvilava, Vasily; Vieten, Maximilian; Oestreich, Robert; Woschko, Dennis; Steinert, Moritz; Boldog, Ishtvan; Bulánek, Roman; Fokina, Natalie A.; Schreiner, Peter R.; Janiak, Christoph
• Is Part Of: CrystEngComm. Volume 24:Issue 43(2022)
• Page Start: 7530
• Page End: 7534
• Publication Date: 2022-10-12
• Subjects: Crystals -- Periodicals; Crystal growth -- Periodicals; Crystallography -- Periodicals; Cristaux -- Périodiques; Cristaux -- Croissance -- Périodiques; Cristallographie -- Périodiques; 548
• DOI: 10.1039/d2ce01170k
• Languages: English
• ISSNs: 1466-8033

Abstract

Abstract : HHUD-3, based on a bulky barrel shaped ligand, possesses 35%+ missing linker defects, essential for accessible porosity. With SBET = 890 m 2 g −1 (N2 ), HHUD-3 features higher CH4 but lower CO2 and H2 adsorption compared to UiO-66. Abstract : The first use of a bulky barrel-shaped ligand is demonstrated in HHUD-3, with accessible porosity only feasible for a defect structure. With 35%+ missing linker defects and S BET = 890 m 2 g −1 (N2 ), HHUD-3 features higher CH4 but lower CO2 and H2 adsorption than UiO-66.