Insights into the spontaneous multi-scale supramolecular assembly in an ionic liquid-based extraction system. Issue 42 (20th October 2022)

• Record Type: Journal Article
• Authors: Chen, Baihua; Shi, Ce; Xiong, Shijie; Wu, Kaige; Yang, Yanqiu; Mu, Wanjun; Li, Xingliang; Yang, Yuchuan; Shen, Xinghai; Peng, Shuming
• Is Part Of: Physical chemistry chemical physics. Volume 24:Issue 42(2022)
• Page Start: 25950
• Page End: 25961
• Publication Date: 2022-10-20
• Subjects: Chemistry, Physical and theoretical -- Periodicals; 541.3
• DOI: 10.1039/d2cp03389e
• Languages: English
• ISSNs: 1463-9076

Abstract

Abstract : Spontaneous multi-scale supramolecular assembly (MSSA) and multi-scale selectivity (MSS) are realized in ionic liquid-based extraction systems, which can pave the way for the development of supramolecular chemistry and separation chemistry. Abstract : Herein, we report a four-step mechanism for the spontaneous multi-scale supramolecular assembly (MSSA) process in a two-phase system concerning an ionic liquid (IL). The complex ions, elementary building blocks (EBBs), [EBB] n clusters and macroscopic assembly (MA) sphere are formed step by step. The porous large-sized [EBB] n clusters in the glassy state can hardly stay in the IL phase and they transfer to the IL–water interface due to both electroneutrality and amphiphilicity. Then, the clusters undergo random collision in the interface driven by the Marangoni effect and capillary force thereafter. Finally, a single MA sphere can be formed owing to supramolecular interactions. To our knowledge, this is the first example realizing spontaneous whole-process supramolecular assembly covering microscopic, mesoscopic and macroscopic scales in extraction systems. The concept of multi-scale selectivity (MSS) is therefore suggested and its mechanism is revealed. The selective separation and solidification of metal ions can be realized in a MSSA-based extraction system depending on MSS. In addition, insights into the physicochemical characteristics of ILs from microscopic, mesoscopic to macroscopic scales are provided, and especially, the solvation effect of ILs on the large-sized clusters leading to the phase-splitting is examined. It is quite important that the polarization of uranyl in its complex, the growing of uranyl clusters in an IL as well as the glassy material of uranyl are investigated systematically on the basis of both experiment and theoretical calculations in this work.