Novel process design and techno-economic simulation of methanol synthesis from blast furnace gas in an integrated steelworks CCUS system. (December 2022)

• Record Type: Journal Article
• Authors: Porter, Richard T.J.; Cobden, Paul D.; Mahgerefteh, Haroun
• Is Part Of: Journal of CO₂ utilization. Volume 66(2022)
• Publication Date: 2022-12
• Subjects: Process design -- Methanol synthesis -- CO2 hydrogenation -- Iron & steel -- Technoeconomic analysis; Carbon dioxide -- Periodicals; Carbon dioxide -- Environmental aspects -- Periodicals; Carbon dioxide mitigation -- Periodicals; Carbon dioxide; Carbon dioxide -- Environmental aspects; Carbon dioxide mitigation; Periodicals; 628.53205
• DOI: 10.1016/j.jcou.2022.102278
• Languages: English
• ISSNs: 2212-9820

Abstract

Abstract: A novel process design and techno-economic performance assessment for methanol synthesis from Blast Furnace Gas (BFG) is presented. Methanol synthesis using BFG as a feedstock, based on direct CO2 hydrogenation at commercial scale was simulated using Aspen Plus software to evaluate its technical performance and economic viability. The applied process steps involve first conditioning BFG using adsorption based desulfurisation, water-gas shift, dehydration, then separation of components into N2, CO2 and H2 rich streams using pressure swing adsorption. The H2 stream and a fraction of the CO2 stream are fed to a methanol synthesis system, while the remaining CO2 may be considered for geological storage in a Carbon Capture, Utilization and Storage (CCUS) case, or not in a Carbon Capture Utilization (CCU) case. Techno-economic analysis confirms methanol production from BFG is economically attractive under certain conditions, with Levelized Cost of Methanol production (LCOMeOH) calculated to be 344.61 £/tonne-methanol, and costs of CO2 avoided of − 20.08 £/tonne-CO2 for the CCU process and 9.01 £/tonne-CO2 for the CCUS process when using a set of baseline engineering assumptions. Sensitivity analysis of the process simulation explores opportunities for optimising the methanol synthesis system in terms of the impact of reactor size and/or recycle ratio on LCOMeOH. Economic viability of the CCU(S) processes is also found to be highly dependent on the cost of the feedstock BFG. Future cost savings as compared to business-as-usual steel production by 2030 in consideration of expected increases in the carbon price are estimated to be 10.59 £/tonne-steel for CCU and 24.61 £/tonne-steel for CCUS. Highlights: A novel process design and techno-economic performance assessment for methanol synthesis from blast furnace gas is presented. Methanol production from blast furnace gas is economically attractive under certain conditions. Sensitivity analysis around methanol synthesis reactor size and loop recycle ratio is presented. Economic viability of the processes is found to be highly dependent on the cost of the feedstock blast furnace gas.