Enhanced electroreduction of CO2 by Ni–N–C catalysts from the interplay between valency and local coordination symmetry. Issue 42 (11th October 2022)

• Record Type: Journal Article
• Authors: Shin, Dongyup; Choi, Hansol; An, Jihun; Sohn, Chang Ho; Choi, Chang Hyuck; Shin, Hyeyoung; Kim, Hyungjun
• Is Part Of: Journal of materials chemistry. Volume 10:Issue 42(2022)
• Page Start: 22523
• Page End: 22530
• Publication Date: 2022-10-11
• Subjects: Materials -- Research -- Periodicals; Chemistry, Analytic -- Periodicals; Environmental sciences -- Research -- Periodicals; 543.0284
• DOI: 10.1039/d2ta05844h
• Languages: English
• ISSNs: 2050-7488

Abstract

Abstract : Symmetry breaking and valency change of Ni–N–C catalysts endow a CO2 electroreduction activity. Abstract : Many studies have focused on atomically dispersed metal–nitrogen–carbon (Me–N–C) catalysts owing to their unique chemistry and high catalytic activities. Me–N–C catalysts have active centers resembling metalloporphyrins; thus, being heterogeneous analogs of homogeneous catalysts, their catalytic characteristics can be described by organometallic principles. In this regard, the high electrochemical activity of Ni–N–C catalysts for carbon dioxide reduction reactions (CO2 RRs) is particularly difficult to understand because Ni 2+ is a d 8 species with a chemically inert axial site for intermediate binding in a square-planar ligand field. To resolve such a conundrum, we investigated the effects of different coordination geometries and Ni spin states on CO2 RR activities—both of which influence the chemical activity of the Ni center. We used the grand-canonical density functional theory (GC-DFT) and the occupation matrix control method to properly include a finite potential effect, and to control the oxidation state of the Ni center, respectively. We elucidated that the generation of Ni + directly impacts the CO2 RR activity by providing strong intermediate binding energies to the Ni center, and a defective coordination environment is essential for stabilizing the Ni + oxidation state. Our present study identifying governing factors for the high catalytic activity of Ni–N–C catalysts provides a design principle to develop high-performing catalysts for CO2 RR.