Polymer networks of imine-crosslinked metal–organic cages: tuneable viscoelasticity and iodine adsorption. Issue 86 (13th October 2022)

• Record Type: Journal Article
• Authors: Schneider, Matthew L.; Campbell, Jonathan A.; Slattery, Ashley D.; Bloch, Witold M.
• Is Part Of: Chemical communications. Volume 58:Issue 86(2022)
• Page Start: 12122
• Page End: 12125
• Publication Date: 2022-10-13
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/d2cc04969d
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : The solution-state structure of MOP-15 is elucidated, enabling its direct use as a porous monomer for covalent polymer networks. Abstract : The solution-state structure of an amine-functionalised Cu24 L24 cage (MOP-15) is elucidated, enabling its direct covalent crosslinking into a series of highly tuneable organogels. These soft porous networks exhibit up to a ∼10-fold increase in capacity for iodine compared to the discrete cage precursor.