Natural Soft/Rigid Superlattices as Anodes for High‐Performance Lithium‐Ion Batteries. (11th August 2020)

• Record Type: Journal Article
• Authors: Bai, Wei; Gao, Jingyu; Li, Kun; Wang, Gongrui; Zhou, Tengfei; Li, Pengju; Qin, Shengyong; Zhang, Genqiang; Guo, Zaiping; Xiao, Chong; Xie, Yi
• Is Part Of: Angewandte Chemie. Volume 132:Number 40(2020)
• Page Start: 17647
• Page End: 17651
• Publication Date: 2020-08-11
• Subjects: Lithium-ion batteries -- misfit compounds -- niobium -- PbS -- soft/rigid superlattices; Chemistry -- Periodicals; 540
• DOI: 10.1002/ange.202008197
• Languages: English
• ISSNs: 0044-8249

Abstract

Abstract: Volume expansion and poor conductivity are two major obstacles that hinder the pursuit of the lithium‐ion batteries with long cycling life and high power density. Herein, we highlight a misfit compound PbNbS3 with a soft/rigid superlattice structure, confirmed by scanning tunneling microscopy and electrochemical characterization, as a promising anode material for high performance lithium‐ion batteries with optimized capacity, stability, and conductivity. The soft PbS sublayers primarily react with lithium, endowing capacity and preventing decomposition of the superlattice structure, while the rigid NbS2 sublayers support the skeleton and enhance the migration of electrons and lithium ions, as a result leading to a specific capacity of 710 mAh g −1 at 100 mA g −1, which is 1.6 times of NbS2 and 3.9 times of PbS. Our finding reveals the competitive strategy of soft/rigid structure in lithium‐ion batteries and broadens the horizons of single‐phase anode material design. Abstract : A misfit compound, PbNbS3, has a soft/rigid superlattice structure. Soft PbS sublayers contribute the capacity, and the rigid NbS2 sublayers maintain the stability and dominate the conductivity, thus promoting the migration of electrons and lithium ions, leading to competitive lithium‐ion anode performance.