Comparison and synergistic effect analysis on supercritical water gasification of waste thermoplastic plastics based on orthogonal experiments. (15th December 2022)

• Record Type: Journal Article
• Authors: Chen, Jingwei; Fu, Liangyu; Tian, Ming; Kang, Siyi; E, Jiaqiang
• Is Part Of: Energy. Volume 261:Part B(2022)
• Publication Date: 2022-12-15
• Subjects: Waste thermoplastic plastics -- Supercritical water gasification -- Gasification characteristics -- Orthogonal experiments -- Comprehensive evaluation; Power resources -- Periodicals; Power (Mechanics) -- Periodicals; Energy consumption -- Periodicals; 333.7905
• DOI: 10.1016/j.energy.2022.125104
• Languages: English
• ISSNs: 0360-5442

Abstract

Abstract: Supercritical water gasification (SCWG) is a clean technology of utilizing waste plastics. In this paper, the SCWG characteristics of waste thermoplastic plastics, including polypropylene (PP), polyethylene (PE), and polyethylene terephthalate (PET), and a mixed plastic, were investigated by using the orthogonal experiments. The effect of reaction temperature, reaction time and mass concentration on gasification characteristics was explored and the optimum conditions was obtained. The results show that the reaction temperature has the most important positive effect on the SCWG of PP, PE and PET. The factors that influence the SCWG of mixed plastic follow the order: mass concentration > reaction temperature > reaction time. SCWG efficiency of the mixed plastic is higher than that of all single plastic due to the synergistic effect of different plastic composition. The optimal conditions of mixed plastic are 800 °C, 25 min and 5 wt% and the maximum GE is 106.8%. The energy and exergy efficiency of SCWG system at 650 °C are 47.2% and 37.3%, respectively. The GWP of 1 kg hydrogen produced by SCWG of PE is 3.57 kgCO2 eq. The water recycling can greatly reduce the exergy cost of the SCWG system. This study will promote the industrialization of SCWG technology of plastics. Graphical abstract: Image 1 Highlights: The orthogonal SCWG experiments of waste thermoplastic plastics are conducted. The effect of factors on different plastics gasification in SCW are analyzed. The optimal conditions for SCWG of different plastics are obtained. The SCWG characteristics of single plastic and mixed plastic are compared.