Influence of Preparation Conditions on the Structure of MCM-41 and Catalytic Performance of Ru/MCM-41 in Benzene Hydrogenation. (February 2014)

• Record Type: Journal Article
• Authors: Liao, Hongguang; Ouyang, Donghong; Zhang, Jing; Xiao, Yanjuan; Liu, Pingle; Hao, Fang; You, Kuiyi; Luo, He'an
• Is Part Of: Journal of chemical research. Volume 38:Number 2(2014)
• Page Start: 90
• Page End: 95
• Publication Date: 2014-02
• Subjects: benzene hydrogenation -- cyclohexene selectivity -- MCM-41 -- Ru/MCM-41 -- preparation conditions; Chemistry -- Research -- Periodicals; Chemistry -- Periodicals; 540.5
• DOI: 10.3184/174751914X13892022601610
• Languages: English
• ISSNs: 1747-5198

Abstract

The influence of the preparation conditions on the structures of mesoporous molecular sieve MCM-41 were studied. The prepared MCM-41 samples were characterised by nitrogen physical adsorption–desorption, powder X-ray diffraction, transmission electron microscopy, FT-IR spectroscopy, thermo gravimetric analysis, differential scanning calorimetry and water/benzene static adsorption technologies. Ru/MCM-41 catalysts were then prepared by double solvent impregnation method and tested for benzene hydrogenation to cyclohexene. The structure characteristics of MCM-41 have a great effect on cyclohexene selectivity in benzene hydrogenation process. Ruthenium supported on MCM-41 with moderate surface area, larger pore size and pore volume, better long-range-order of hexagonal mesoporous shows better catalytic performance for benzene hydrogenation to cyclohexene.