Direct acylation and alkynylation of hydrocarbons via synergistic decatungstate photo-HAT/nickel catalysis. Issue 85 (5th October 2022)

• Record Type: Journal Article
• Authors: Liu, Wenfeng; Ke, Yang; Liu, Chuhan; Kong, Wangqing
• Is Part Of: Chemical communications. Volume 58:Issue 85(2022)
• Page Start: 11937
• Page End: 11940
• Publication Date: 2022-10-05
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/d2cc04408k
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : Herein, we describe a protocol for the direct and selective acylation and alkynylation of the C(sp 3 )–H bonds of saturated hydrocarbons by synergistic decatungstate photo-HAT and nickel catalysis. Abstract : Herein, we describe a protocol for the direct and selective acylation and alkynylation of the C(sp 3 )–H bonds of saturated hydrocarbons by synergistic decatungstate photo-HAT and nickel catalysis. This method, using cheap and easy-to-synthesize TBADT as a HAT photocatalyst, exhibits excellent site selectivity. A wide variety of high-value ketones, amides, esters, and diverse alkynes can be efficiently constructed from abundant hydrocarbon feedstocks.