[3+2] click chemistry approach to tetrazine containing polymers. Issue 44 (6th October 2022)

• Record Type: Journal Article
• Authors: Chavez, David E.; Tappan, Bryce C.; Kuehl, Valerie A.; Schmalzer, Andrew M.; Leonard, Philip W.; Wu, Ruilian; Imler, Greg H.; Parrish, Damon A.
• Is Part Of: RSC advances. Volume 12:Issue 44(2022)
• Page Start: 28490
• Page End: 28493
• Publication Date: 2022-10-06
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1039/d2ra05339j
• Languages: English
• ISSNs: 2046-2069

Abstract

Abstract : We report a [3+2] cycloaddition using 3, 6-bis-propargyloxy-1, 2, 4, 5-tetrazine and azides to synthesize energetic polymers containing 1, 2, 4, 5-tetrazine within the scaffold. Abstract : We report a [3+2] cycloaddition using 3, 6-bis-propargyloxy-1, 2, 4, 5-tetrazine and azides to synthesize energetic polymers containing 1, 2, 4, 5-tetrazine within the scaffold. This work also includes [3+2] cycloaddition to crosslink azide containing glycidyl azide polymer (GAP). These reactions provide pathways for incorporation of 1, 2, 4, 5-tetrazine into novel energetic materials using click-chemistry and provide an alternative polymer curing approach.