Selective enrichment of Brønsted acid site in 8-membered ring channels of MOR zeolite to enhance the catalytic reactivity of dimethyl ether carbonylation. (14th December 2022)

• Record Type: Journal Article
• Authors: Chen, Feng; Feng, Xiao-Bo; Zhang, Li-Yun; Zhao, Jing-Ping; He, Zi-Meng; Yi, Feng-Jiao; Zhao, Xiao-Yan; Cao, Jing-Pei
• Is Part Of: Chemical engineering science. Volume 263(2022)
• Publication Date: 2022-12-14
• Subjects: BAS distribution -- HMOR zeolite -- B8-MR -- DME Carbonylation; Chemical engineering -- Periodicals; Génie chimique -- Périodiques; Chemical engineering; Periodicals; Electronic journals; 660
• DOI: 10.1016/j.ces.2022.118110
• Languages: English
• ISSNs: 0009-2509

Abstract

Highlights: The acid distribution in HMOR zeolite can be oriented-tailored. The amount of B8-MR in HM-PN-2 is twice as much as the HM sample. The reactivity of DME carbonylation can be largely enhanced over HM-PN-2. Outstanding stability can be further realized over pyridine modified HMOR. Abstract: Directional adjusting of the distribution of Brønsted acid site (BAS) in zeolite to control its catalytic performance is highly attractive but remains challenging. This study aims to tailor the distribution of BAS in 8-membered ring (B8-MR ) of H-Mordenite (HMOR) by adding aniline or p -phenylenediamine as additives to the sol‐gel. The results reveal that the number of B8-MR is significantly increased but with a slight change in the number of BAS in 12-membered ring channels. When using dimethyl ether (DME) carbonylation as the probe reaction, the conversion of DME to methyl acetate over the synthesized HMOR zeolite is increased by nearly 2 times. Our finding not only provides a facile strategy to regulate the acid distribution in different channels of the HMOR zeolite but also offers a promising candidate for the catalytic DME carbonylation, which is a critical intermediate step for ethanol synthesis from syngas.