2-Iodoxybenzenesulfonic Acid-Catalysed oxidation of Primary and Secondary Alcohols with Oxone in Cetyl Trimethylammonium Bromide Micelles at Room Temperature. (July 2014)

• Record Type: Journal Article
• Authors: Liu, Yangyang; Wang, Boliang
• Is Part Of: Journal of chemical research. Volume 38:Number 7(2014)
• Page Start: 427
• Page End: 431
• Publication Date: 2014-07
• Subjects: 2-iodoxybenzene sulfonic acid/oxone -- CTAB micelles -- selective oxidation -- alcohol -- green chemistry; Chemistry -- Research -- Periodicals; Chemistry -- Periodicals; 540.5
• DOI: 10.3184/174751914X14031774189763
• Languages: English
• ISSNs: 1747-5198

Abstract

A mild and green protocol for alcohol oxidation using 2-iodoxybenzene sulfonic acid/oxone at room temperature in CTAB micelles has been developed. Typically, secondary benzyl alcohols were oxidised to ketones and primary benzyl alcohols to aldehydes in good yields in 2 h. Under harsher conditions (100 °C/24 h), aliphatic alcohols were oxidised to ketones or organic acids in moderate to high yields.