1, 4, 7-Trimethyl-1, 4, 7-Triazacyclononane as a Low-Loading Catalyst: CuBr–tmtacn Catalysed Glaser reaction of Acetylenes. (June 2014)

• Record Type: Journal Article
• Authors: Sun, Jian; Zhang, Hua-He; Wang, Jian-Qiang; Li, Jing-Hua
• Is Part Of: Journal of chemical research. Volume 38:Number 6(2014)
• Page Start: 362
• Page End: 364
• Publication Date: 2014-06
• Subjects: 1, 3-diynes -- tmtacn -- low-loading catalyst -- Glaser reaction; Chemistry -- Research -- Periodicals; Chemistry -- Periodicals; 540.5
• DOI: 10.3184/174751914X681970
• Languages: English
• ISSNs: 1747-5198

Abstract

1, 4, 7-Trimethyl-1, 4, 7-triazacyclononane (tmtacn, a cyclic trident-ligand) has been developed as a facile and efficient catalyst for Cu-catalysed homocoupling of terminal alkynes at room temperature. A variety of 1, 3-diynes have been synthesised in excellent yields with a catalyst loading on a scale of 0.1–0.5 mol% CuBr–tmtacn.