Revealing two-stage phase transition process in defective KTaO3 under inelastic interactions. (1st January 2023)

• Record Type: Journal Article
• Authors: Iancu, D.; Zarkadoula, E.; Mihai, M.D.; Burducea, C.; Burducea, I.; Straticiuc, M.; Zhang, Y.; Weber, W.J.; Velişa, G.
• Is Part Of: Scripta materialia. Number 222(2023)
• Publication Date: 2023-01-01
• Subjects: Perovskite -- Ion channeling -- Molecular dynamics -- Ion-induced annealing -- Two-stage process; Materials -- Periodicals; Metallurgy -- Periodicals; Metalen; Legeringen; Materiaalkunde; Metals, metalworking and machinery industries; Metals; Electronic journals; 620.11
• DOI: 10.1016/j.scriptamat.2022.115032
• Languages: English
• ISSNs: 1359-6462

Abstract

Abstract: The interactions of ions with defective KTaO3 has been studied by irradiating pre-damaged single crystal KTaO3 with 5 MeV C, 7 MeV Si and 12 MeV O ions at 300 K. By exploring these processes in KTaO3, the results show that, for a pre-damaged fractional disorder level of 0.3 and inelastic electronic energy loss, Se, ≥ 4.65 keV/nm (7 MeV Si ions), the synergistic interaction of Se with defects enables amorphous ion track creation. At lower values of Se (5 MeV C and 12 MeV O), minor increases in disorder are observed initially over a region of depth at an ion fluence of 10 ions/nm 2, which may be due to dissolution of pre-existing interstitial or amorphous clusters; however, with further increase in ion fluence, a transition from irradiation-induced disorder production to ionization-induced damage recovery processes, not previously reported in KTaO3, is observed. Graphical abstract: Image, graphical abstract