Isomeric Dithienothiophene‐Based Hole Transport Materials: Role of Sulphur Atoms Positions on Photovoltaic Performance of Inverted Perovskite Solar Cells. (5th August 2022)

• Record Type: Journal Article
• Authors: Yang, Jie; Huang, Jiachen; Zhang, Chao; Sun, Huiliang; Li, Bolin; Wang, Yimei; Feng, Kui; Liao, Qiaogan; Bai, Qingqing; Niu, Li; Wang, Hua; Guo, Xugang
• Is Part Of: Advanced functional materials. Volume 32:Number 41(2022)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2022-08-05
• Subjects: green solvents -- hole‐transport materials -- inverted perovskite solar cells -- isomers; Materials -- Periodicals; Chemical vapor deposition -- Periodicals; 620.11
• DOI: 10.1002/adfm.202206311
• Languages: English
• ISSNs: 1616-301X

Abstract

Abstract: Hole transport materials (HTMs) are of great significance to improve the efficiency and long‐term stability of perovskite solar cells (PVSCs). Herein, a series of new HTMs based on isomeric dithienothiophene (DTT) are designed and synthesized. Effects of sulphur (S) atoms positions on defect passivation and performance of PVSCs are systematically investigated through theoretical computation, X‐ray diffraction, X‐ray photoelectron spectroscopy, etc. The three molecules display noticeable isomeric effect in energy level, light absorption, and hole mobility. With S atoms varied from bottom‐bottom‐bottom in 3T‐1 to bottom‐bottom‐top in 3T‐2, then to bottom‐top‐bottom in 3T‐3, the grown perovskite crystallite on the corresponding HTMs shows more homeogenous film morphology and less pinhole traps. Meanwhile, nonradiative recombination losses can be suppressed and hole extraction efficiency at HTM/perovskite surface can be improved from 3T‐1 to 3T‐3. As a result, the remarkable improvement of short‐circuit current density nd open‐circuit voltage in inverted perovskite solar cells can be realized with increasing the sulphur atoms contribution to the molecular conjugation. More importantly, 3T‐3‐based dopant‐free HTM achieves a top power conversion efficiency of 19.23% in PVSCs with good device stability under green solvent processing. These results demonstrate the role of S atoms positions in HTMs on photovoltaic performance of PVSCs and the potential of DTT in developing eco‐friendly HTMs toward efficient PVSCs. Abstract : The effects of sulphur atoms positions of dithienothiophene on electronic property of hole‐transport materials and performances of perovskite solar cells are systematically investigated. The positional variation of sulphur atoms in dithienothiophene not only gradually improves electron delocalization and enhances hole mobility but also effectively suppresses nonradiative recombination of perovskite solar cells.