Comparative of MIL101(Cr) and nano‐MIL101(Cr) Electrode as an Electrochemical Hydrogen Peroxide Sensor. Issue 10 (12th April 2022)

• Record Type: Journal Article
• Authors: Salman, Fırat; Kazıcı, Hilal Çelik; Gülcan, Mehmet
• Is Part Of: Electroanalysis. Volume 34:Issue 10(2022)
• Page Start: 1598
• Page End: 1609
• Publication Date: 2022-04-12
• Subjects: Electrocatalysis -- Hydrogen peroxide -- Metal-organic framework -- MIL101(Cr) -- Nafion glassy carbon electrode; Electrochemical analysis -- Periodicals; Chemistry, Analytical -- Periodicals; Electrochemistry -- Periodicals; 543.4
• DOI: 10.1002/elan.202200005
• Languages: English
• ISSNs: 1040-0397

Abstract

Abstract: Herein, an electrochemical sensor for the detection of H2 O2 based on nafion glassy carbon electrode modified with MIL101(Cr) and nano ‐MIL101(Cr) are developed and its electrochemical characterizations analyzed by CV and CA. In comparison with the NGCE, MIL101/NGCE and nano ‐MIL101/NGCE, the nano ‐MIL101/NGCE showed a sharp redox peak specific to H2 O2 was obtained in the phosphate‐calibrated solution. nano ‐MIL101/NGCE exhibited good linear response in terms of the relationship between peak currents and concentrations as from 0 to 650 μM ( R 2 =0.99), with a low limit of detection 3.8 μM, high sensitivity 986 μA mM −1 cm −2 and nano ‐MIL101/NGCE exhibited ideal repeatability, reproducibility, stability and the interference‐free perception of H2 O2 . Abstract :