Hole‐Storage Enhanced a‐Si Photocathodes for Efficient Hydrogen Production. (14th April 2021)

• Record Type: Journal Article
• Authors: Zhang, Doudou; Du, Minyong; Wang, Pengpeng; Wang, Hui; Shi, Wenwen; Gao, Yuying; Karuturi, Siva; Catchpole, Kylie; Zhang, Jian; Fan, Fengtao; Shi, Jingying; Liu, Shengzhong
• Is Part Of: Angewandte Chemie. Volume 133:Number 21(2021)
• Page Start: 12073
• Page End: 12079
• Publication Date: 2021-04-14
• Subjects: alkaline medium -- amorphous silicon -- ferrihydrite -- hydrogen production -- photoelectrochemical; Chemistry -- Periodicals; 540
• DOI: 10.1002/ange.202100078
• Languages: English
• ISSNs: 0044-8249

Abstract

Abstract: Ferrihydrite (Fh) has been demonstrated as an effective interfacial layer for photoanodes to achieve outstanding photoelectrochemical (PEC) performance for water oxidation reaction owing to its unique hole‐storage function. However, it is unknown whether such a hole‐storage layer can be used to construct highly efficient photocathodes for hydrogen evolution reaction (HER). In this work, we report Fh interfacial engineering of amorphous silicon photocathode (with nickel as HER cocatalyst) achieving a photocurrent density of 15.6 mA cm −2 at 0 V vs. the reversible hydrogen electrode and a half‐cell energy conversion efficiency of 4.08 % in alkaline solution, outperforming most of reported a‐Si based photocathodes including multi‐junction configurations integrated with noble metal cocatalysts in acid solution. Besides, the photocurrent density is maintained above 14 mA cm −2 for 175 min with 100 % Faradaic efficiency for HER in alkaline solution. Our results demonstrate a feasible approach to construct efficient photocathodes via the application of a hole‐storage layer. Abstract : An outstanding PEC performance of amorphous silicon photocathode is reported with a record 15.6 mA cm −2 current density at 0 V vs. RHE, the maximum ABPE of 4.08 %, and a sustained operation for 175 min for hydrogen production with 100 % Faradaic efficiency in harsh alkaline media. This remarkable performance is made possible by Fh interfacial engineering which facilitates the electron transfer to the surface Ni cocatalyst but blocks the holes.