Facile nanoplastics formation from macro and microplastics in aqueous media. (15th November 2022)

• Record Type: Journal Article
• Authors: Peller, Julie R.; Mezyk, Stephen P.; Shidler, Sarah; Castleman, Joe; Kaiser, Scott; Faulkner, Richard F.; Pilgrim, Corey D.; Wilson, Antigone; Martens, Sydney; Horne, Gregory P.
• Is Part Of: Environmental pollution. Volume 313(2022)
• Publication Date: 2022-11-15
• Subjects: Polyethylene -- Polymeric nanoparticles -- Particle size -- Water contaminants -- Solubilizer -- Plastics; Pollution -- Periodicals; Pollution -- Environmental aspects -- Periodicals; Environmental Pollution -- Periodicals; Pollution -- Périodiques; Pollution -- Aspect de l'environnement -- Périodiques; Pollution -- Effets physiologiques -- Périodiques; Pollution; Pollution -- Environmental aspects; Periodicals; Electronic journals; 363.73
• DOI: 10.1016/j.envpol.2022.120171
• Languages: English
• ISSNs: 0269-7491

Abstract

Abstract: The immense production of plastic polymers combined with their discordancy with nature has led to vast plastic waste contamination across the geosphere, from the oceans to freshwater reservoirs, wetlands, remote snowpacks, sediments, air and multiple other environments. These environmental pollutants include microplastics (MP), typically defined as small and fragmented plastics less than 5 mm in size, and nanoplastics (NP), particles smaller than a micrometer. The formation of micro and nanoplastics in aqueous media to date has been largely attributed to fragmentation of plastics by natural (i.e., abrasion, photolysis, biotic) or industrial processes. We present a novel method to create small microplastics (≲ 5 μm) and nanoplastics in water from a wide variety of plastic materials using a small volume of a solubilizer liquid, such as n -dodecane, in combination with vigorous mixing. When the suspensions or solutions are subjected to ultrasonic mixing, the particle sizes decrease. Small micro- and nanoparticles were made from commercial, real world and waste (aged) polyethylene, polystyrene, polycarbonate and polyethylene terephthalate, in addition to other plastic materials and were analyzed using dark field microscopy, Raman spectroscopy and particle size measurements. The presented method provides a new and simple way to create specific size distributions of micro- and nanoparticles, which will enable expanded research on these plastic particles in water, especially those made from real world and aged plastics. The ease of NP and small MP formation upon initial mixing simulates real world environments, thereby providing further insight into the behavior of plastics in natural settings. Graphical abstract: Image 1 Highlights: Many plastic materials are readily water solubilized as micro and nanoplastics. The solubilization of plastics creates suspended particles of different sizes. Smaller nanoplastics (NP) can be prepared using ultrasound mixing. Aqueous NP solutions are stable in the presence of other dissolved solutes. Solubilized real-world NP have different shapes and sizes than commercial NP.