Detection and separation of silver ions from industrial wastewaters using fluorescent d-glucose carbon nanosheets and quaternary silver indium zinc sulphide quantum dots. (October 2022)

• Record Type: Journal Article
• Authors: May, Bambesiwe M.; Fakayode, Olayemi J.; Mashale, Kedibone N.; Bambo, Mokae F.; Mishra, Ajay K.; Nxumalo, Edward N.
• Is Part Of: Journal of water process engineering. Volume 49(2022)
• Publication Date: 2022-10
• Subjects: Ag+ ions -- Carbon nanosheets -- Quaternary quantum dots -- Industrial wastewater -- Heavy metals; Water-supply engineering -- Periodicals; Saline water conversion -- Periodicals; Seawater -- Distillation -- Periodicals; Sanitary engineering -- Periodicals; Sewage -- Purification -- Periodicals; 627
• DOI: 10.1016/j.jwpe.2022.102944
• Languages: English
• ISSNs: 2214-7144

Abstract

Abstract: Carbon nanomaterials are essential for functions such as electronic connectivity, wastewater purification, energy and environmental sustainability applications. In this report, fluorescent carbon nanosheet was obtained from d -glucose (F-GCNS) via a low-temperature in-situ pyrolysis. The as-synthesized F-GCNS were characterized using conventional spectroscopic and microscopic techniques. Furthermore, the nanosheets were used to detect and separate silver ions (Ag+) from aqueous solutions with a detection limit (LOD) of 1.74 ppm and about 98.42 ± 0.69 % removal for concentrations ranging between 0 and 20 ppm and 100 and 200 ppm respectively. Comparably, at all concentrations, the nanosheets exhibited an LOD better than that of the quaternary silver indium zinc sulphide quantum dots (Glu-AISZ) (LOD = 7.96, R2 0.6524 for 0–20 ppm and 28.01, R2 = 0.95418 for 30–100 ppm respectively). The F-GCNS showed attractiveness for simultaneous detection and removal of heavy metal pollutants from industrial wastewater. Graphical abstract: Unlabelled Image Highlights: d -Glucose transformed to a fluorescent carbon nanosheet using in-situ pyrolysis. Effect of pH and temperature on photoluminescence properties investigated Comparative sensing performance analyzed with ternary quantum dots Nanosheet showed better LOD at all concentrations than quantum dots. Both materials separated Ag + from industrial wastewater containing Pb 2+ and Ti 2+ .