Simple synthesis of a hierarchical LiMn0.8Fe0.2PO4/C cathode by investigation of iron sources for lithium-ion batteries. Issue 40 (15th September 2022)

• Record Type: Journal Article
• Authors: Li, Yuanchao; Xing, Baoyan; Zhang, Huishuang; Wang, Mengjie; Yang, Li; Xu, Guangri; Yang, Shuting
• Is Part Of: RSC advances. Volume 12:Issue 40(2022)
• Page Start: 26070
• Page End: 26077
• Publication Date: 2022-09-15
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1039/d2ra04427g
• Languages: English
• ISSNs: 2046-2069

Abstract

Abstract : A hierarchical porous LiMn0.8 Fe0.2 PO4 /C (N-LMFP) was synthesized by a simple solid-state method beneficial for engineering applications. The fine particle and hierarchical porous structure enable a superior rate performance of the N-LMFP sample. Abstract : Iron (Fe) substitution is an effective strategy for improving the electrochemical performance of LiMnPO4 which has poor conductivity. Herein, we focus on investigating the effect of substitution of Mn with different iron sources, on the structure and electrochemical performances of the LiMnPO4 materials. The Fe-substituted LiMnPO4 /C composites were synthesized via a simple and rational solid-state method, and will be of benefit for engineering applications. The characterization of the materials shows an obvious influence of the iron sources on structure and morphology. The N-LMFP material prepared using soluble FeNO3 as iron sources exhibits an excellent rate capacity of 122 mA h g −1 at 5C, and superior cyclability with a capacity retention of 98.9% after 400 cycles at 2C. The enhanced rate capability and cycling stability of N-LMFP are the result of the lowered electron/ion resistance and the improved reversibility of the reaction, that originates from the homogeneous fine particles and hierarchical structure with large mesopores. This research provides significant guidelines for designing an LiMnPO4 cathode with a high performance.