Modular silacyclopropenes: synthesis and application for Si–H containing substrate functionalization. Issue 79 (15th September 2022)

• Record Type: Journal Article
• Authors: Nobis, Matthias; Inoue, Shigeyoshi; Rieger, Bernhard
• Is Part Of: Chemical communications. Volume 58:Issue 79(2022)
• Page Start: 11159
• Page End: 11162
• Publication Date: 2022-09-15
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/d2cc04565f
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : We report an effective and versatile method to functionalize Si–H containing substrates with monofunctional silacyclopropenes as modular units in a hydrosilylation reaction. Abstract : A method to functionalize Si–H containing substrates with vinyl substituted silacyclopropenes has been developed. This provides an efficient and versatile technique to generate multi-functional silacyclopropene derivatives, ranging from small molecules to polymeric materials like polysiloxanes. Thus, access is given to a new class of functionalized materials that exhibits potential in a variety of possible applications.