Dual role of oxygen-related defects in the luminescence kinetics of AlN:Mn2+. Issue 37 (7th September 2022)

• Record Type: Journal Article
• Authors: Lazarowska, Agata; Kamiński, Mikołaj; Cherepy, Nerine J.; Mahlik, Sebastian; Liu, Ru-Shi
• Is Part Of: Dalton transactions. Volume 51:Issue 37(2022)
• Page Start: 14297
• Page End: 14305
• Publication Date: 2022-09-07
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/d2dt02171d
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : This study presents the impact of temperature and pressure on AlN:Mn 2+ luminescence kinetics. Abstract : This study presents the impact of temperature and pressure on AlN:Mn 2+ luminescence kinetics. Unusual behavior of Mn 2+ optical properties during UV excitation is observed, where a strong afterglow luminescence of Mn 2+ occurs even at low temperatures. When the temperature increases, the contribution of the afterglow luminescence is further enhanced, causing a significant increase in the luminescence intensity. The observed phenomena may be explained by an energy diagram in which the ON –VAl complex in AlN:Mn 2+ plays a key role. Hence the ON –VAl complex defect in AlN:Mn 2+ plays a double role. When the ON –VAl defect is located close to Mn 2+ ions, it is responsible for transferring excitation energy directly to Mn 2+ ions. However, when the ON –VAl defect complex is located far from Mn 2+ ions, its excited state level acts as an electron trap responsible for afterglow luminescence. Additionally, three models have been tested to explain the structure of the emission spectrum and the strong asymmetry between the excitation and emission spectra. From the most straightforward configuration coordinate diagram through the configuration coordinate diagram model assuming different elastic constants in the excited and ground-states ending by a model based on the Jahn–Teller effect. We proved that only the Jahn–Teller effect in the excited 4 T1 electronic state with spin–orbit coupling could fully explain the observed phenomena. Finally, high-pressure spectroscopic results complemented by the calculations of Racah parameters and the Tanabe–Sugano diagram are presented.