An aryl diimine cobalt(i) catalyst for carbonyl hydrosilylation. Issue 77 (8th September 2022)
- Record Type:
- Journal Article
- Title:
- An aryl diimine cobalt(i) catalyst for carbonyl hydrosilylation. Issue 77 (8th September 2022)
- Main Title:
- An aryl diimine cobalt(i) catalyst for carbonyl hydrosilylation
- Authors:
- Sharma, Anuja
So, Sangho
Kim, Jun-Hyeong
MacMillan, Samantha N.
Baik, Mu-Hyun
Trovitch, Ryan J. - Abstract:
- Abstract : Aldehyde and ketone hydrosilylation turnover frequencies of up to 330 s −1 have been achieved using a phosphine-substituted aryl diimine cobalt catalyst. Abstract : Through the application of a redox-innocent aryl diimine chelate, the discovery and utilization of a cobalt catalyst, ( Ph2 PPr ADI)Co, that exhibits carbonyl hydrosilylation turnover frequencies of up to 330 s −1 is described. This activity is believed to be the highest ever reported for metal-catalyzed carbonyl hydrosilylation.
- Is Part Of:
- Chemical communications. Volume 58:Issue 77(2022)
- Journal:
- Chemical communications
- Issue:
- Volume 58:Issue 77(2022)
- Issue Display:
- Volume 58, Issue 77 (2022)
- Year:
- 2022
- Volume:
- 58
- Issue:
- 77
- Issue Sort Value:
- 2022-0058-0077-0000
- Page Start:
- 10793
- Page End:
- 10796
- Publication Date:
- 2022-09-08
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/d2cc04089a ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 23865.xml