Diverse reactivity of an iron–aluminium complex with substituted pyridines. Issue 77 (8th September 2022)
- Record Type:
- Journal Article
- Title:
- Diverse reactivity of an iron–aluminium complex with substituted pyridines. Issue 77 (8th September 2022)
- Main Title:
- Diverse reactivity of an iron–aluminium complex with substituted pyridines
- Authors:
- Gorgas, Nikolaus
White, Andrew J. P.
Crimmin, Mark R. - Abstract:
- Abstract : The reaction of an Fe–Al complex with an array of substituted pyridines is reported. Abstract : The reaction of an Fe–Al complex with an array of substituted pyridines is reported. Depending on the substitution pattern of the substrate site-selective sp 2 or sp 3 C–H bond activation is observed. A series of reaction products are observed based on (i) C–Al bond formation, (ii) C–C bond formation by nucleophilic addition or (iii) deprotonation of the β-diketiminate ligand. A divergent set of mechanisms involving a common intermediate is proposed.
- Is Part Of:
- Chemical communications. Volume 58:Issue 77(2022)
- Journal:
- Chemical communications
- Issue:
- Volume 58:Issue 77(2022)
- Issue Display:
- Volume 58, Issue 77 (2022)
- Year:
- 2022
- Volume:
- 58
- Issue:
- 77
- Issue Sort Value:
- 2022-0058-0077-0000
- Page Start:
- 10849
- Page End:
- 10852
- Publication Date:
- 2022-09-08
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/d2cc04498f ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 23865.xml