Terpolymerizations of CO2, Propylene Oxide and DL‐Lactide Catalyzed by Zn‐Fe DMC Catalysts with Quaternary Ammonium Salts. Issue 8 (24th February 2020)

• Record Type: Journal Article
• Authors: Liu, Ningzhang; Gu, Chuanhai; Chen, Mengting; Zhang, Junan; Yang, Wen; Zhan, Aihong; Zhang, Kewei; Lin, Qiang; Zhu, Linhua
• Is Part Of: ChemistrySelect. Volume 5:Issue 8(2020)
• Page Start: 2388
• Page End: 2394
• Publication Date: 2020-02-24
• Subjects: carbon dioxide fixation -- block copolymers -- terpolymerizations -- mechanical ball milling -- bimetallic cyanide catalyst; Chemistry -- Periodicals; 540.5
• DOI: 10.1002/slct.201904461
• Languages: English
• ISSNs: 2365-6549

Abstract

Abstract: Polymers synthesized from carbon dioxide (CO2 ) and epoxy compounds are biodegradable materials and therefore are potentially very important in tackling the plastic pollutions. In this work, we synthesized Zn–Fe DMC catalysts with quaternary ammonium salts as a cocatalyst via ball milling. The obtained catalysts showed excellent activity (turn over frequency up to TOF=5.65 g‐polymer/g‐Zn h −1 ) in the terpolymerizations of CO2, propylene oxide and DL‐Lactide, yielding the biodegradable polymers with average relative molecular mass between 9.8×10 3 and 1.1×10 4, and the polydispersity index in the range of 1.7‐2.0. The main advantages of using mechanochemical method for the synthesis of the catalysts lie in the easy adjustment of co‐catalyst loading and its operational simplicity. Abstract : Zn–Fe DMC catalysts with quaternary ammonium salts via ball milling was investigated in the alternating terpolymerization of poly(propylene carbonate) with CO2, PO and DL‐lactide. The obtained catalysts show excellent activity (turn over frequency up to TOF=5.65 g‐polymer/g‐Zn h −1 ) in the terpolymerizations. And the average relative molecular mass of terpolymers is between 9.8×10 3 and 1.1×10 4 .