Ethyl cellulose based self-healing adhesives synthesized via RAFT and aromatic schiff-base chemistry. (15th December 2020)

• Record Type: Journal Article
• Authors: Gong, Xuanang; Cheng, Zenghui; Gao, Shishuai; Zhang, Daihui; Ma, Yufeng; Wang, Jifu; Wang, Chunpeng; Chu, Fuxiang
• Is Part Of: Carbohydrate polymers. Volume 250(2020)
• Publication Date: 2020-12-15
• Subjects: Adhesives -- Ethyl cellulose -- Schiff base -- Self-Healing -- Vanillin; Polysaccharides -- Periodicals; Polysaccharides -- Periodicals; Polysaccharides -- Périodiques; Electronic journals; 547.78
• DOI: 10.1016/j.carbpol.2020.116846
• Languages: English
• ISSNs: 0144-8617

Abstract

Highlights: Ethyl cellulose acted as the backbone to synthesize bottlebrush copolymers. Renewable vanillin provided aldehyde groups in copolymers using RAFT strategy. Schiff base formation led to the fabrication of self-healing adhesives. A high self-healing efficiency was realized due to the bottlebrush structures. Abstract: In this work, reversible addition-fragmentation chain transfer (RAFT) polymerization and Schiff base chemistry was combined to fabricate self-healing adhesives. An esterification reaction was first performed to prepare ethyl cellulose based macroinitiators. Then, a "grafting from" RAFT of vanillin methacrylate and lauryl methacrylate was used to obtain graft copolymers. DSC result showed that the glass transition temperature was manipulated via changing the ratio of vanillin and fatty acids moieties. NMR spectrum analysis demonstrated the presence of aldehyde groups, which were available for the dynamic crosslinking to generate a network as self-healing adhesives. The adhesive test showed that the shear strength could reach 0.81 MPa with a self-healing efficiency of 98.7 %. The bottlebrush structures of copolymers and reversibility of Schiff base chemistry might collaboratively contribute to the high self-healing efficiency. This study provides a facile way to fabricate high-performance self-healing adhesives from ethyl cellulose and renewable resources.