Improved wet shear strength in eco-friendly starch-cellulosic adhesives for woody composites. (15th December 2020)

• Record Type: Journal Article
• Authors: Yin, Hao; Zheng, Peitao; Zhang, Erbing; Rao, Jiuping; Lin, Qiaojia; Fan, Mizi; Zhu, Zhiqiang; Zeng, Qinzhi; Chen, Nairong
• Is Part Of: Carbohydrate polymers. Volume 250(2020)
• Publication Date: 2020-12-15
• Subjects: Carbohydrate -- Newspaper -- Formaldehyde-free -- Resin -- Wood; Polysaccharides -- Periodicals; Polysaccharides -- Periodicals; Polysaccharides -- Périodiques; Electronic journals; 547.78
• DOI: 10.1016/j.carbpol.2020.116884
• Languages: English
• ISSNs: 0144-8617

Abstract

Highlights: A green, easy and low cost approach was developed for making bio-adhesives. Waste newspaper powder is an essential component of starch-cellulosic adhesive. The cured adhesive displayed excellent water resistance. The formaldehyde-free adhesive showed potential woody composites application. Abstract: Development of eco-friendly adhesives from renewable biomass has attracted considerable attention in recent years. Here, we present a novel approach via combination of waste newspaper (WNP) powder, oxidized glutinous rice starch, and polyamidoamine-epichlorohydrin (PAE) to prepare a formaldehyde-free starch-cellulosic adhesive (SCA) for woody composites. The oxidation treatment made the carboxyl/carbonyl groups more available in starch. Plywood bonded by the optimum SCA with 50 wt% of the WNP powder showed a wet shear strength of 0.83 MPa exceeding that of the oxidized starch adhesive by 130.5 %. During the curing process of SCA, the oxidized starch and WNP fiber participated into the crosslinking reaction with PAE via ester and ether bonds, as evidenced by FTIR analysis. The resulting cured adhesive had enhanced crystalline structures, thermal properties, hydrophobicity, wet-cohesion, rheological properties, and adhesiveness to wood. The SCA showed great potential in wood composites as an alternative to formaldehyde-derived adhesives.