Discovery of First Magnesium Fluorooxoborate with Stable Fluorine Terminated Framework for Deep‐UV Nonlinear Optical Application. (20th May 2021)

• Record Type: Journal Article
• Authors: Xia, Ming; Li, Fuming; Mutailipu, Miriding; Han, Shujuan; Yang, Zhihua; Pan, Shilie
• Is Part Of: Angewandte Chemie. Volume 133:Number 26(2021)
• Page Start: 14771
• Page End: 14777
• Publication Date: 2021-05-20
• Subjects: borate -- deep-ultraviolet -- fluorooxoborate -- functionalized chromophore -- nonlinear optical materials; Chemistry -- Periodicals; 540
• DOI: 10.1002/ange.202103657
• Languages: English
• ISSNs: 0044-8249

Abstract

Abstract: The generated light can be tuned to cover almost the entire spectral range from deep‐ultraviolet to terahertz wavelengths by utilizing the nonlinear optical crystals with a simple frequency doubling process. Among them, the discovery of novel candidates for the production of deep‐ultraviolet light is by extension a great challenge toward realizing the vast potential. Actually, the availability for this process mainly depends on whether the critical performance can be well coexisted in one practical crystal. Herein, the first magnesium fluorooxoborate MgB5 O7 F3 was synthesized as a new competitive candidate for deep‐ultraviolet nonlinear optical application. It has a sufficiently large nonlinearity and a deep‐ultraviolet phase matching wavelength, indicating that it holds great potential for the production of coherent light below 200 nm. The critical performance enhancement of MgB5 O7 F3 when compared with its isomorphic phases was demonstrated and discussed. More importantly, we proposed that fluorooxoborate system with the general formula of MB5 O7 F3 (M=divalent metal) possesses stable fluorine terminated framework, which makes them tend to retain their crystallized space groups unchanged. Abstract : The first magnesium fluorooxoborate MgB5 O7 F3 was synthesized as a new competitive candidate for deep‐UV NLO application. More importantly, we demonstrated that fluorooxoborate system with the general formula of MB5 O7 F3 (M=divalent metal) possesses stable fluorine terminated framework, which makes them tend to retain their crystallized space groups unchanged.