A classical [V10O28]6− anion templated high-nuclearity silver thiolate cluster. Issue 66 (28th July 2022)

• Record Type: Journal Article
• Authors: Li, Li; Zhu, Yanjie; Han, Baoliang; Wang, Qiongyi; Zheng, Luming; Feng, Lei; Sun, Di; Wang, Zhi
• Is Part Of: Chemical communications. Volume 58:Issue 66(2022)
• Page Start: 9234
• Page End: 9237
• Publication Date: 2022-07-28
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/d2cc03003a
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : The largest known polyoxovanadate-templated silver nanocluster (Ag50 ) was synthesized, and the box-like {V10 O28 @Ag50 } structure displays the geometric inheritance from the internal decavanadate to the silver skeleton. Abstract : Polyoxovanadates (POVs) as templates are still scarcely observed in silver clusters. Herein, the largest known POV-based silver cluster (Ag50 ) was synthesized, which is a core–shell conformation composed of the in situ generated classical [V10 O28 ] 6− core and Ag50 shell, constrained by the S- and O-donor ligands with a specific distribution. Such {V10 O28 @Ag50 } structure displays geometric inheritance from the D 2h symmetric decavanadate to the silver skeleton. The solution behavior, solid-state stability and photoelectric properties are discussed in detail. This work provides enlightenment for the further construction of POV-templated high-nuclearity silver clusters.