Enhanced thermal energy storage performance of molten salt for the next generation concentrated solar power plants by SiO2 nanoparticles: A molecular dynamics study. (1st October 2022)

• Record Type: Journal Article
• Authors: Xian, Lei; Chen, Lei; Tian, Heqing; Tao, Wen-Quan
• Is Part Of: Applied energy. Volume 323(2022)
• Publication Date: 2022-10-01
• Subjects: Molten salts -- SiO2 nanoparticles -- Thermal energy storage -- Molecular dynamics; Power (Mechanics) -- Periodicals; Energy conservation -- Periodicals; Energy conversion -- Periodicals; 621.042
• DOI: 10.1016/j.apenergy.2022.119555
• Languages: English
• ISSNs: 0306-2619

Abstract

Highlights: Chloride molten salt-nanoparticle composite materials were proposed and designed. Thermal energy storage characteristics were accurately predicted by molecular dynamics simulation. Amorphous SiO2 greatly improves the heat transfer performance of composite materials. A compressed interface layer is formed between the base fluid and the nanoparticles. The compressed interface layer is mainly composed of cations and has a thickness of about 5 Å. Abstract: Chloride molten salt is the most promising thermal energy storage materials for the next generation concentrated solar power (CSP) plants. In this work, to enhance the thermal performance of KNaCl2 molten salts, composited thermal energy storage (CTES) materials based on amorphous SiO2 nanoparticles and KNaCl2 were proposed and designed under the guidance of the material composition design strategy. The molecular dynamics simulation method has been conducted to investigate the thermal storage properties and analyze the mechanism of heat transfer improvement from the perspective of microstructure evolution, thermal diffusion properties and energy changes. Thermal conductivity, viscosity, and specific heat capacity of CTES materials at high temperatures with different volume fractions of nanoparticles were predicted to provide reference data for the design of heat transfer systems in CSP plants. The study discovered that increasing the volume fraction of nanoparticles increases the thermal conductivity and specific heat capacity of the systems significantly, with the maximum increase of 25.28% and 7.87%, respectively. Moreover, the enhancement of heat transfer characteristics is the result of the formation of a compressed interface layer with a thickness 5 Å on the outer surface of SiO2 nanoparticles. This work has important guiding significance for the material selection and composition design of molten salt-nanoparticle composite materials used for next-generation CSP plants.