Preparation and investigation of pulse co-deposited duplex nanoparticles reinforced Ni-Mo coatings under different electrodeposition parameters. Issue 20 (15th October 2022)

• Record Type: Journal Article
• Authors: Xu, Yiku; Gao, Yue; Fan, Mingyuan; Lu, Xinyu; Chen, Yongnan; Zhao, Qinyang
• Is Part Of: Ceramics international. Volume 48:Issue 20(2022)
• Page Start: 29629
• Page End: 29640
• Publication Date: 2022-10-15
• Subjects: Ni-Mo nanocomposite Coatings -- Duplex particles -- Wear and corrosion resistance -- Surface modification; Ceramics -- Periodicals; Céramique industrielle -- Périodiques; Ceramics; Periodicals; Electronic journals; 666
• DOI: 10.1016/j.ceramint.2022.06.217
• Languages: English
• ISSNs: 0272-8842

Abstract

Abstract: In this work, Ni–Mo–SiC–TiN nanocomposite coatings were deposited on aluminium alloy by pulse electrodeposition with various electrodeposition parameters. The influences of the pulse frequency and duty cycle on the phase structure, morphology, mechanical and corrosion performance of the coatings were systematically investigated. The results showed that with increasing pulse frequency and decreasing duty cycle, the content of embedded duplex nanoparticles increased, and the grains refined gradually. The nanocomposite coating that was prepared at 20% duty cycle and 1000 Hz pulse frequency exhibited compact, uniform, and fine microstructures with the maximum incorporation of nanoparticles (6.81 wt% TiN and 1.72 wt% SiC). The wear rate and average friction coefficient then declined to 4.812 × 10 −4 mm 3 /N·m and 0.13, respectively, with a maximum microhardness of 519 HV. Simultaneously, the corrosion current density was reduced to 3.11 μA/cm 2, and a maximum impedance of 34888 Ω cm 2 was exhibited. The uniformly distributed duplex nanoparticles acted as a hindrance, which consequently supported the enhancement of corrosion and wear resistance. By investigating the variation of the pulse diffusion layer with electrical parameters, it was discovered that when the crystallite size is equivalent to or smaller than the diffusion layer thickness, it would be easier to cross the diffusion layer to incorporate in the coating. Additionally, the effects of various duty cycles and pulse frequencies on the nucleation process of the grains were discussed.