Electrochemical upgrading of biomass-derived 5-hydroxymethylfurfural and furfural over oxygen vacancy-rich NiCoMn-layered double hydroxides nanosheets. Issue 11 (12th May 2021)

• Record Type: Journal Article
• Authors: Liu, Biying; Xu, Shaojun; Zhang, Man; Li, Xin; Decarolis, Donato; Liu, Yuqian; Wang, Yuchen; Gibson, Emma K.; Catlow, C. Richard A.; Yan, Kai
• Is Part Of: Green chemistry. Volume 23:Issue 11(2021)
• Page Start: 4034
• Page End: 4043
• Publication Date: 2021-05-12
• Subjects: Environmental chemistry -- Industrial applications -- Periodicals; Environmental management -- Periodicals; 660
• DOI: 10.1039/d1gc00901j
• Languages: English
• ISSNs: 1463-9262

Abstract

Abstract : Rational design of low-cost and active electrocatalysts is crucial for upgrading of biomass-derived chemicals. Abstract : Rational design of low-cost and active electrocatalysts is crucial for upgrading of biomass-derived chemicals. Here, we report highly efficient catalysts ternary NiCoMn-layered double hydroxides (NiCoMn-LDHs) nanosheets which are oxygen vacancy-rich, produced under controllable conditions for the electrooxidation of both 5-hydroxymethylfurfural (HMF) to 2, 5-furandicarboxylic acid (FDCA) and furfural to furoic acid (FurAc) under mild conditions, respectively. Electrochemical tests showed that the oxidation of HMF and furfural occurred prior to the oxidation of water at lower applied potentials with NiCoMn-LDHs catalysts. High yields of FDCA (91.7%) and FurAc (92.4%) were achieved in 2.5 h using 1.15 nm thick NiCoMn-LDHs nanosheets under the optimal conditions. The mechanism for the superior performance, high durability, and good faradaic efficiency has been elucidated by comprehensive characterization, which confirmed that ultrathin nanosheets expose more Co-NiOOH active sites with oxygen vacancies, facilitating the synergistic effect between HMF and furfural oxidation reaction on Co–Ni and Mn 2+ states. The oxygen vacancy-rich NiCoMn-LDHs nanosheet catalysts present a novel and energy-efficient solution to obtain upgraded biochemicals.