Effects of types and content of clay minerals on reservoir effectiveness for lacustrine organic matter rich shale. (1st November 2022)

• Record Type: Journal Article
• Authors: Hou, Lian-hua; Wu, Song-tao; Jing, Zhen-hua; Jiang, Xiao-hua; Yu, Zhi-chao; Hua, Ganlin; Su, Ling; Yu, Cong; Liao, Feng-rong; Tian, Hua
• Is Part Of: Fuel. Volume 327(2022)
• Publication Date: 2022-11-01
• Subjects: Oil saturation index (OSI) -- Pore structure -- Oil occurrence -- Unconventional oil and gas -- Shale oil -- Free oil; Fuel -- Periodicals; Coal -- Periodicals; Coal; Fuel; Periodicals; 662.6
• DOI: 10.1016/j.fuel.2022.125043
• Languages: English
• ISSNs: 0016-2361

Abstract

Highlights: The shales deposited in saline water have lower clay mineral contents than those in fresh water. The clay minerals mainly fill in the dispersed pores in saline water but occur along the strata to form laminae in fresh water. Thermal effect controls the clay mineral transformation leading the shale hydrocarbon storage space to alter. Abstract: As a promising supplement of China's petroleum production, the lacustrine shale, compared with the marine shale, is characterized by higher clay mineral content, which has significant impacts on the hydrocarbon reservoir quality. Controlled by the paleo-lacustrine background and thermal maturity, the clay mineral contents vary tremendously in different shale systems. This study targets on three shale series formed in different basin types, namely the Lucaogou Formation shale (Junggar Basin), the Chang 7 Member shale (Ordos Basin), and the Qingshankou Formation shale (Songliao Basin), where the Junggar Basin was a saline lacustrine basin and the latter two were freshwater-brackish lacustrine basins. We find that the composition and content of clay minerals are considerably varied among the three shales that the clay mineral content of the Lucaogou formation shale is smaller than that of the Chang 7 Member and Qingshankou Formation, and the content of illite in the Chang 7 shale is lower than that in the Qingshankou shale. The occurrence of clay minerals has crucial effects on pore structures, that is the pore-filling clays has indiscernible contribution to the storage space, like in the Lucaogou shale, but those developing along the shale laminae can improve the storage capacities to form inter-granular pores and micro-fractures such as in Chang 7 Member and Qingshankou Formation. The development of clay mineral-related pores and fractures is controlled by thermal maturity (Ro) and affected by the content of terrigenous minerals. This pore structure alteration derived by the clay mineral occurrence types further affects the hydrocarbon contents. In the Lucaogou shale, the oil content is inversely proportional to clay mineral contents, while in Qingshankou Formation, the oil content is even higher than that of the adjacent felsic silt laminae due to the favorable development of micro-fractures and inter-granular pores in clay mineral laminae. The high clay mineral content in lacustrine shales in China make it necessary to investigate the clay mineral evolution to evaluate the hydrocarbon generation potential, pore structures, hydrocarbon contents, and hydrocarbon accumulation mechanisms in shale systems.