In situ inelastic neutron scattering of mixed CH4–CO2 hydrates. (1st November 2022)

• Record Type: Journal Article
• Authors: Cladek, Bernadette R.; Ramirez-Cuesta, A.J.; Everett, S. Michelle; McDonnell, Marshall T.; Daemen, Luke; Cheng, Yongqiang; Brant Carvalho, Paulo H.B.; Tulk, Christopher; Tucker, Matthew G.; Keffer, David J.; Rawn, Claudia J.
• Is Part Of: Fuel. Volume 327(2022)
• Publication Date: 2022-11-01
• Subjects: Natural gas hydrates -- CO2 Sequestration -- methane-CO2 exchange -- Neutron scattering -- Molecular dynamics simulations; Fuel -- Periodicals; Coal -- Periodicals; Coal; Fuel; Periodicals; 662.6
• DOI: 10.1016/j.fuel.2022.125197
• Languages: English
• ISSNs: 0016-2361

Abstract

Highlights: CH4 -CO2 and Xe hydrates are measured with inelastic neutron scattering at 5–190 K. Molecular dynamics simulations are used to model the INS spectra for each sample. Vibrational spectra show that the presence of CO2 in hydrates stiffens the network. INS spectra are used to analyze the impact of CH4 and CO2 on hydrate lattice modes. Abstract: An abundant source of CH4 can be found in natural hydrate deposits. Recent demonstration of CH4 recovery from hydrates via CO2 exchange has revealed the potential as a fuel source that also provides a medium for carbon sequestration. It is vital to understand the structural and dynamic impacts of guest variation in CH4, CO2, and mixed hydrates and link the results to the stability of various deposits in nature, harvesting methane, and sequestering CO2 . Molecular vibrations are examined in CH4, CO2, and mixed CH4 -CO2 hydrates at 5 and 190 K and Xe hydrates for comparison. Inelastic neutron scattering (INS) is an ideal spectroscopy technique to observe the dynamic modes in the hydrate structure and enclathrated CH4, as it is extremely sensitive to 1 H. The presence of CO2 in hydrates tightens the lattice. It introduces more active librational modes to the host lattice, while hindering the motion of CH4 in mixed CH4 -CO2 hydrate at 5 K. At 190 K, a large broadening of the CH4 librational modes indicates disorder in the structure leading to dissociation.