Synthesis of organophosphates starting from α-hydroxyphosphonates. (27th May 2019)

• Record Type: Journal Article
• Authors: Kiss, Nóra Z.; Rádai, Zita; Szabó, Réka; Aichi, Youness; Laasri, Laila; Sebti, Said
• Is Part Of: Phosphorus, sulfur, and silicon and the related elements. Volume 194:Number 4/6(2019)
• Page Start: 370
• Page End: 371
• Publication Date: 2019-05-27
• Subjects: α-Hydroxyphosphonates -- phosphates -- Moroccan phosphates -- rearrangement; Sulfur compounds -- Periodicals; Organosulfur compounds -- Periodicals; Phosphorus compounds -- Periodicals; Organophosphorus compounds -- Periodicals; Silicon compounds -- Periodicals; Organosilicon compounds -- Periodicals; 546
• DOI: 10.1080/10426507.2018.1547722
• Languages: English
• ISSNs: 1042-6507

Abstract

Abstract: α-Hydroxyphosphonates were successfully converted to the corresponding phosphates applying the phospha-Brook rearrangement under phase transfer catalytic conditions. Among several possible catalysts tested, K2 CO3, Cs2 CO3, as well as modified Moroccan phosphates were found to be suitable. Graphical Abstract: uf0001