Theoretical Study of Effect of the Number of N, N-dimethyl-4-nitroaniline Units in Novel "Parallel Connection" Chromophores on Its Nonlinear Optical Properties. (22nd December 2011)

• Record Type: Journal Article
• Authors: Zhang, Chao-Zhi; Cao, Hui; Guo, Zhao-Bing
• Other Names: Kar T. Academic Editor.; Reis H. Academic Editor.; Sliwa M. Academic Editor.
• Is Part Of: ISRN physical chemistry. Volume 2012(2012)
• Publication Date: 2011-12-22
• Subjects: Chemistry, Physical and theoretical -- Periodicals; Chemistry, Physical and theoretical; 35.10 physical chemistry: general; Periodicals; Electronic journals; 541
• DOI: 10.5402/2012/262563
• Languages: English
• ISSNs: 2090-7761

Abstract

Abstract : Design of "parallel connection" chromophores could give a way of acquiring effective chromophores. The semiempirical method ZINDO was employed to study relationship between static first hyperpolarizabilities of "parallel connection" chromophores and the number of parallel nonconjugated N, N-dimethyl-4-nitroaniline (DMNA) units in the chromophore. The results show that the chromophore containing three parallel non-conjugated DMNA units exhibits the highest static first hyperpolarizability, which is 1.8 times that of chromophore DMNA. However, static first hyperpolarizabilities of the chromophores containing four or five DMNA units are very small. The absorption maximum wavelength (λ max ) of "parallel connection" chromophores is remarkably shorter (34.9 nm–38.1 nm) than that of 1DMNA . Therefore, the "parallel connection" chromophore containing three DMNA units would be an effective chromophore with a large first hyperpolarizability and a good optical transparency. It could give a useful suggestion for designing effective chromophores containing parallel non-conjugated D- π -A units.