Identifying the Correlation between Structural Parameters and Anisotropic Magnetic Properties in IMnV Semiconductors: A Possible Room‐Temperature Magnetism. Issue 33 (17th July 2022)

• Record Type: Journal Article
• Authors: Yoo, Byung Il; Lee, Nahyun; Lamichhane, Bipin; Bang, Joonho; Song, Hyun Yong; Park, Byung Cheol; Lee, Kyu Hyoung; Kim, Seong‐Gon; Kim, Sung Wng
• Is Part Of: Advanced materials. Volume 34:Issue 33(2022)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2022-07-17
• Subjects: antiferromagnets -- defect‐induced ferromagnetism -- layered structures -- magnetic anisotropy -- magnetic semiconductors; Materials -- Periodicals; Chemical vapor deposition -- Periodicals; 620.11
• DOI: 10.1002/adma.202200074
• Languages: English
• ISSNs: 0935-9648

Abstract

Abstract: Layer‐structured materials are of central importance in a wide range of research fields owing to their unique properties originating from their two dimensionality and anisotropy. Herein, quasi‐2D layer‐structured IMnV (I: alkali metals and V: pnictogen elements) compounds are investigated, which are potential antiferromagnetic (AFM) semiconductors. Single crystals of IMnV compounds are successfully grown using the self‐flux method and their electronic and magnetic properties are analyzed in correlation with structural parameters. Combined with theoretical calculations, the structural analysis indicates that the variation in the bonding angle between VMnV is responsible for the change in the orbital hybridization of Mn and V, predominantly affecting their anisotropic semiconducting properties. Anisotropy in the magnetic properties is also found, where AFM ordering is expected to occur in the in‐plane direction, as supported by spin–structure calculations. Furthermore, a possible ferromagnetic (FM) transition is discussed in relation to the vacancy defects. This study provides a candidate material group for AFM and FM spintronics and a basis for exploring magnetic semiconductors in quasi‐2D layer‐structured systems. Abstract : A comprehensive study of the single‐crystal growth of IMnV (I: alkali metals and V: pnictogen elements) compound series, physical property measurements of their intrinsic anisotropic character, and their theoretical electronic and magnetic structures suggests a possible room‐temperature magnetic semiconductor. These experimental and computational results broaden the scope of intrinsic magnetic semiconductors in quasi‐2D layer‐structured systems for spintronics.