One‐pot facile synthesis of Cu‐SAPO‐34 via addition of tetraethylenepentamine and its enhanced catalytic activity in selective catalytic reduction of NOx with NH3. Issue 10 (25th June 2022)

• Record Type: Journal Article
• Authors: Cao, Yue; Chen, Boyuan; Dong, Yongli; Zhu, Yujun; Li, Zhibin
• Is Part Of: Journal of chemical technology & biotechnology. Volume 97:Issue 10(2022)
• Page Start: 2834
• Page End: 2843
• Publication Date: 2022-06-25
• Subjects: selective catalytic reduction of NOx by NH3 -- Cu‐SAPO‐34 -- one‐pot method -- H2O and SO2 resistance -- tetraethylenepentamine -- isolated Cu2+ species; Biotechnology -- Periodicals; Chemistry, Technical -- Periodicals; Chemical engineering -- Periodicals; Industries -- Environmental aspects -- Periodicals; 660
• DOI: 10.1002/jctb.7152
• Languages: English
• ISSNs: 0268-2575

Abstract

Abstract: BACKGROUND: A series of Cu‐SAPO‐34 samples were prepared with different copper sources and addition of tetraethylenepentamine (TEPA) by a one‐pot method, which were applied for selective catalytic reduction of NO x with ammonia (NH3 ‐SCR). RESULTS: Various measurements were carried out to investigate the effect of TEPA addition and copper sources used on sample properties. The results indicated that Cu‐SAPO‐34 obtained with the addition of TEPA using copper citrate (Cu‐SAPO‐34‐TC) displayed over 90% NO x conversion at 150–500 °C and excellent H2 O and SO2 resistance in NH3 ‐SCR. This is because the addition of TEPA can control the formation of isolated Cu 2+ species located at the junction of D6R in CHA cage, Site (I), which is regarded as a more easily approachable site to adsorbates (NH3 and NO) than others, thus leading to the excellent NH3 ‐SCR performance. Further study demonstrated that the Cu‐SAPO‐34‐TC catalyst shows much wider temperature window and more hydrothermal stability due to a greater amount of surface isolated Cu 2+, fewer Si islands and more Al(IV) species. CONCLUSIONS: The excellent activity of the Cu‐SAPO‐34‐TC catalyst can be attributed to the addition of TEPA, which is beneficial for controlling the isolated Cu 2+ at Site (I) as well as inhibiting the aggregation of CuO species. Various characterizations also confirm that more surface Cu 2+ can be produced using copper citrate as copper source. © 2022 Society of Chemical Industry (SCI).