Simulation of anoxic lenses as exporters of reactivity in alluvial aquifer sediments. (1st October 2022)

• Record Type: Journal Article
• Authors: Babey, Tristan; Boye, Kristin; Tolar, Bradley; Engel, Maya; Noël, Vincent; Perzan, Zach; Kumar, Naresh; Francis, Christopher A.; Bargar, John R.; Maher, Kate
• Is Part Of: Geochimica et cosmochimica acta. Volume 334(2022)
• Page Start: 119
• Page End: 134
• Publication Date: 2022-10-01
• Subjects: Alluvial aquifers -- Dual-domain systems -- Sulfur cycling -- Iron cycling -- Particulate/colloidal organic carbon; Geochemistry -- Periodicals; Meteorites -- Periodicals; Géochimie -- Périodiques; Météorites -- Périodiques; Geochemie; Astrochemie; Electronic journals; 551.905
• DOI: 10.1016/j.gca.2022.07.018
• Languages: English
• ISSNs: 0016-7037

Abstract

Abstract: Sedimentary interfaces between contrasting hydrogeological facies in alluvial aquifers drive the development of biogeochemical interfaces that influence subsurface and surface water quality. Here, we calibrate a reactive transport model on a series of dual-domain column experiments, where centimeter-scale, low-permeability, organic-rich anoxic lenses are embedded in coarser-grained aquifer material. Simulations explicitly account for C, Fe, and S cycling at the interface between the lenses and the aquifer in water-saturated conditions. Our results highlight the role of fine-grained, organic-rich inclusions not only as sources or sinks for redox-sensitive species, but also as exporters of nutrients that stimulate downgradient biogeochemical cycling. By releasing large amounts of organic carbon into the surrounding aquifer, such lenses drive the development of proximal secondary reduction zones ("halos"), characterized by high microbial activity ( e.g., sulfate reduction) and accumulation of reduced reaction products ( e.g., iron sulfide). If similar secondary reduction zones develop within the hydraulically conductive domain of an aquifer, they would be highly susceptible to changes in hydrologic conditions, for instance oxygen pulses associated with seasonal snowmelt. Our results also emphasize the limitations of relying solely on aqueous species measurements to inform reactivity in systems where fast redox cycling and/or sizeable particulate transport may limit the signature of reactivity in the dissolved phase.