Ultrahigh electric‐field‐induced strain in KNN‐based piezoelectric ceramics sintered in reducing atmosphere. Issue 11 (24th July 2022)

• Record Type: Journal Article
• Authors: Dong, Zhihao; Cen, Zhenyong; Hui, Kezhen; Xu, Ze; Zhao, Peiyao; Wang, Xiaohui
• Is Part Of: Journal of the American Ceramic Society. Volume 105:Issue 11(2022)
• Page Start: 6744
• Page End: 6754
• Publication Date: 2022-07-24
• Subjects: inverse piezoelectric property -- lead‐free ceramics -- reducing atmosphere -- temperature stability; Ceramics -- Periodicals; 620.1405
• DOI: 10.1111/jace.18652
• Languages: English
• ISSNs: 0002-7820

Abstract

Abstract: With the goals of sustainable development adopted by more and more nations, the lead‐free trend of multilayer ceramic actuators has become a widely recognized consensus. Sintering in a reducing atmosphere is a necessary approach for preparing lead‐free ceramics co‐fired with low‐cost nickel internal electrodes. Herein, (1 − x )K0.48 Na0.52 Nb0.96 Ta0.04 O3 – x Sr(Zr0.5 Ti0.5 )O3 + 0.03ZrO2 + 0.08MnO2 (KNNT‐SZT) ceramics were sintered in a reducing atmosphere using a solid‐state reaction. The Sr(Zr0.5 Ti0.5 )O3 (SZT) dopant decreased the Curie temperature TC and the O–T phase transition temperature. The enhanced diffuseness of the ferroelectric phase transition of KNNT‐SZT ceramics is attributed to the element doping and the locally inhomogeneous microstructure. High inverse piezoelectric coefficients d 33 * of 883 and 787 pm/V were obtained for the 8‐ and 9‐mol% SZT‐doped samples, respectively. These results were attributed to the synergistic effect of ferroelectric domains with different sizes. The diffused O–T phase transition significantly improved the piezoelectric temperature stability of the 9‐mol% SZT‐doped sample, whose electric‐field‐induced strain decreased by <10% from room temperature (25°C) to 115°C. The cyclic fatigue test showed that >98% of the initial d 33 * was retained after 10 6 cycles of unipolar electrical loading. The KNNT‐SZT ceramics sintered in a reducing atmosphere possessed excellent inverse piezoelectric properties and are expected to be applied in the field of multilayer ceramic piezoelectric actuators with base metal internal electrodes.