Low‐strain TiP2O7 with three‐dimensional ion channels as long‐life and high‐rate anode material for Mg‐ion batteries. Issue 1 (19th January 2022)

• Record Type: Journal Article
• Authors: Xiong, Fangyu; Jiang, Yalong; Cheng, Li; Yu, Ruohan; Tan, Shuangshuang; Tang, Chen; Zuo, Chunli; An, Qinyou; Zhao, Yunlong; Gaumet, Jean‐Jacques; Mai, Liqiang
• Is Part Of: Interdisciplinary materials. Volume 1:Issue 1(2022)
• Page Start: 140
• Page End: 147
• Publication Date: 2022-01-19
• Subjects: anode material -- intercalation -- low‐strain -- Mg‐ion battery -- TiP2O7; Materials science; Science; Periodicals; 620.11
• DOI: 10.1002/idm2.12004
• Languages: English
• ISSNs: 2767-4401

Abstract

Abstract: Rechargeable magnesium batteries are identified as a promising next‐generation energy storage system, but their development is hindered by the anode−electrolyte−cathode incompatibilities and passivation of magnesium metal anode. To avoid or alleviate these problems, the exploitation of alternative anode materials is a promising choice. Herein, we present titanium pyrophosphate (TiP2 O7 ) as anode materials for magnesium‐ion batteries (MIBs) and investigate the effect of the crystal phase on its magnesium storage performance. Compared with the metastable layered TiP2 O7, the thermodynamically stable cubic TiP2 O7 displays a better rate capability of 72 mAh g −1 at 5000 mA g −1 . Moreover, cubic TiP2 O7 exhibits excellent cycling stability with the capacity of 60 mAh g −1 after 5000 cycles at 1000 mA g −1, which are better than previously reported Ti‐based anode materials for MIBs. In situ X‐ray diffraction technology confirms the single‐phase magnesium‐ion intercalation/deintercalation reaction mechanism of cubic TiP2 O7 with a low volume change of 3.2%. In addition, the density functional theory calculation results demonstrate that three‐dimensional magnesium‐ion diffusion can be allowed in cubic TiP2 O7 with a low migration energy barrier of 0.62 eV. Our work demonstrates the promise of TiP2 O7 as high‐rate and long‐life anode materials for MIBs and may pave the way for further development of MIBs. Abstract : Titanium pyrophosphate with three‐dimensional ion channel is presented as low‐strain anode materials for magnesium‐ion batteries and exhibits high rate capability and long cycling life. In situ X‐ray diffraction technology is employed to confirm the magnesium storage mechanism of titanium pyrophosphate. The magnesium‐ion diffusion behavior in titanium pyrophosphate is investigated by density function theory calculation.