Synthesis, characterization, and thermoluminescence‐based high‐dose neutron and gamma dosimetry study of Al5BO9: Mn, Li nanophosphor. Issue 11 (20th July 2022)

• Record Type: Journal Article
• Authors: Sen, Meghnath; Shukla, Rakesh; Pathak, Nimai; Ali, Kawsar; Sathian, Vilippalil; Tyagi, Avesh K.
• Is Part Of: Journal of the American Ceramic Society. Volume 105:Issue 11(2022)
• Page Start: 6693
• Page End: 6709
• Publication Date: 2022-07-20
• Subjects: Al5BO9: Mn, Li -- food irradiation -- nanophosphor -- neutron dosimetry -- red emitting phosphor -- thermoluminescence; Ceramics -- Periodicals; 620.1405
• DOI: 10.1111/jace.18639
• Languages: English
• ISSNs: 0002-7820

Abstract

Abstract: A near tissue equivalent ( Z eff = 10.8) and wide bandgap ( E g = 5.95 eV) Al5 BO9 : Mn, Li nanophosphor was synthesized by facile gel‐combustion (GC) method, and structural characterizations were performed by XRD, infra‐red, transmission electron microscopy, energy‐dispersive spectra, diffuse reflectance UV–visible spectra, and PL studies. Thermoluminescence (TL) study of Al5 BO9 : Mn, Li revealed the dosimetry glow peak at 542 K, which was absent in undoped Al5 BO9 indicating the importance of Mn dopant. The highest TL response was obtained for the lowest studied dopant concentration (0.1 mol% Mn) that was attributed to the concentration quenching phenomenon. The material is highly reusable with low fading (<10%) up to 110 days. TL response for both thermal neutron and gamma radiations showed excellent linearity within 5 × 10 9 –3 × 10 11 n/cm 2 and 30–5000 Gy, respectively. These studies suggested promising potential of Al5 BO9 : Mn, Li nanophosphor in clinical neutron dosimetry and food irradiation dosimetry applications. Based on the variation of calcination temperature, strategy toward dual application, namely, radiation dosimeter and red‐light emitting phosphor of the material was established. For a better understanding of the TL process, various kinetic parameters like activation energy ( E ), order of kinetics ( b ), and frequency factor ( s ) were evaluated using different methodologies, and the results were found to be in good agreement.